Smart electronic soil sensors could enable farmers to deliver tailored doses of water to their crops, maximizing food production while saving water.
Researchers with King Abdullah University of Science and Technology (KAUST) have developed a rapid and sensitive soil moisture sensor, at the heart of which sits a metal-organic framework (MOF) with a very high affinity for water.
“Irrigation management can help improve crop quality, decrease agricultural costs and preserve water,” said Mohamed Eddaoudi, who led the research along with Khaled Salama, who added that “highly sensitive and selective soil-moisture sensors offer the potential to improve the water management process.”
MOFs may be well suited to soil moisture sensing, Eddaoudi and his collaborators have shown. MOFs are highly porous synthetic materials with a cage-like internal structure that can be tailored to host specific small molecules, including water.
“With their modular porous structure and easy functionalization, MOFs are excellent candidates for sensing applications,” said Osama Shekhah, a research scientist on Eddaoudi’s team. “MOF thin films have already been incorporated into electronic devices, paving the way for their translation to real-world use.”
The MOFs in the study were selected based on their hydrolytic stability, water capacity and water uptake. “We explored several different MOFs, including the highly porous Cr-soc-MOF-1 developed by our group at KAUST that can capture twice its own weight in water,” said Ph.D. student Norah Alsadun.
The team coated the MOFs onto an inexpensive interdigitated electrode microsensor that can be fabricated by inkjet printing or laser etching. When this sensor was inserted into moist soil, air in the MOF was displaced by water, altering its electrical capacitance, a process that can be detected and measured.
Each MOF device was tested in clayey and in loamy sand soil types, which can show significant differences in texture and water-holding capacity. “Notably, the Cr-soc-MOF-1-coated soil-moisture sensor showed the highest sensitivity, of about 450 percent in clayey soil, with a response time of around 500 seconds,” said Salama. The sensor’s response was highly selective for water even when various metal ions were present in the soil.
“We are now designing and developing a portable prototype MOF-based soil moisture sensor that can be easily used for control experiments in real-world, in-field measurements,” noted Eddaoudi.
Photo: Irrigation management in agriculture is one of the most effective tools to protect precious water resources, especially in arid and desert regions of the globe. Photo: ©2023 KAUST; Morgan Bennett Smith
Learn more about creating a sustainable food supply in arid landscapes at the AgraME event, 9-10 October 2023, Dubai.